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Angelina Jolie and Billy Bob Thornton
Before she became Saint Angie, bad girl Angelina Jolie and Billy Bob Thornton got hitched in 2000. After getting tattoos with each other’s names, carrying vials of blood to declare they’re love for each other and publicly kissing and groping one another, their crazy courtship ended in divorce. In court papers, Jolie cited irreconcilable differences and received full custody of their adopted son, Maddox. Although, the two ex-lovers still speak, no word on whether Billy Bob requested his blood back.

WENN